Data.gov is the home of the U.S. Government's Open Data. You can search by type of data, department, or topic. Link and examples:
The US Geological Survey (USGS) is a great source of national data and even some global data. Link and examples:
Other sources:
You can extract census data from American FactFinder (AFF) in Advanced Search.
Discussion of these issues:
Data Sources:
Zip Code to ZCTA Crosswalk
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